Crystal structure of a methimazole-based ionic liquid.

نویسندگان

  • Jamie C Gaitor
  • Manuel Sanchez Zayas
  • Darrel J Myrthil
  • Frankie White
  • Jeffrey M Hendrich
  • Richard E Sykora
  • Richard A O'Brien
  • John T Reilly
  • Arsalan Mirjafari
چکیده

The structure of 1-methyl-2-(prop-2-en-1-ylsulfan-yl)-1H-imidazol-3-ium bromide, C7H11N2S(+)·Br(-), has monoclinic (P21/c) symmetry. In the crystal, the components are linked by N-H⋯Br and C-H⋯Br hydrogen bonds. The crystal structure of the title compound undeniably proves that methimazole reacts through the thione tautomer, rather than the thiol tautomer in this system.

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عنوان ژورنال:
  • Acta crystallographica. Section E, Crystallographic communications

دوره 71 Pt 12  شماره 

صفحات  -

تاریخ انتشار 2015